Download Catalysis: v. 18 (Specialist Periodical Reports) by J.J. Spivey PDF

By J.J. Spivey

There's an expanding problem for chemical and examine associations to discover cost effective and environmentally sound tools of changing typical assets into fuels chemical substances and effort. Catalysts are necessary to those approaches and the Catalysis expert Periodical file sequence serves to focus on significant advancements during this quarter. This sequence presents systematic and targeted reports of issues of curiosity to scientists and engineers within the catalysis box. The insurance comprises all significant parts of heterogeneous and homogeneous catalysis and in addition particular purposes of catalysis resembling NOx keep watch over kinetics and experimental strategies corresponding to microcalorimetry. every one bankruptcy is compiled via well-known specialists inside their expert fields and offers a precis of the present literature. professional Periodical studies supply systematic and precise evaluate insurance in significant components of chemical examine. Compiled via groups of major specialists of their professional fields, this sequence is designed to aid the chemistry neighborhood retain present with the most recent advancements of their box. every one quantity within the sequence is released both every year or biennially and is an excellent reference aspect for researchers.

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Andersson, B. Hedman,Chem. Scr. 1985,25,309. A. D. V. Kruchinina,Russ. J. Inorg. Chem. 1986,31,219. S. Tracey, B. Galeffi, S. Mahjour, Can. J . Chem. 1988,66,2294. B. S. Tracey, Can. J . Chem. 1988,66,2565. S. J. Gresser, Can. J . Chem. 1988,66,2570. S. J. Gresser, B. Galeffi, Inorg. Chem. 1988,27, 157. J. S. M. Parkinson, J . Am. Chem. 1986,108,6229. L. de Meis, J . Bid. Chem. 1984,259,6090. 42 Catalysis 41. 42. M. J. Gresser, J . Cell. Biol. 1989, 107, 189a. V. A. B. Benziger, P. Heaney, D. E.

Therefore, the models of n-butane oxidation on the VPO catalysts proposed to date are based on the hypothetical active sites present on the surface (200) plane. The following types of hypothetical active sites have been proposed to exist on the surface (200) plane [13]: (i) Brarnsted acid sites, probably -POH groups; (ii) Lewis acid sites, probably Vrv and Vv; (iii) one electron redox couple, VV/V'", VIv/VIIr;(iv) two electron redox couple, VV/V"'; (v) bridging oxygen, V-0-V, V-0-P, or VO(P)V; (vi) terminal oxygen, Vv=O, VIv=O; and (vii) activated molecular oxygen, el-peroxo and e2-superoxo species.

Chem. SOC. 1974,96,534. J. E. Radkowsky, J . Am. Chem. 1973,95,7123. P. Hammett, Physical Organic Chemistry, McGraw-Hill: New York, 1970, Ch. 9. F. E. Mesmer, In The Hydrolysis ofcations; Wiley: New York, 1976; 197. J. S. D. , Kluwer Academic Publishers: Boston, 1990, 63. L. Pettersson, I. Andersson, B. Hedman,Chem. Scr. 1985,25,309. A. D. V. Kruchinina,Russ. J. Inorg. Chem. 1986,31,219. S. Tracey, B. Galeffi, S. Mahjour, Can. J . Chem. 1988,66,2294. B. S. Tracey, Can. J . Chem. 1988,66,2565. S.

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